The Chemical and Radiation Diffusion as the Issue of Impact on Weaponry and Military Equipment: Threats, Results and Preventive Measures
Abstract
Purpose. To analytically substantiate the role of chemical and radiation-stimulated diffusion as dominant mechanisms of material degradation in weaponry and military equipment under modern combat conditions, and to develop evidence-based preventive measures for maintaining their operational reliability and combat effectiveness.
Method. The research utilizes theoretical analysis and modeling based on fundamental diffusion laws, including Fick's laws (describing diffusion flux and concentration gradient) and the Arrhenius equation (addressing the dependence of diffusion rate on temperature and activation energy). It also includes an analysis of radiation-stimulated diffusion (RSD) through vacancies and interstitial atoms.
Findings. The study identified a critical impact of diffusion processes on WME, specifically: hydrogen embrittlement of artillery barrels and aviation chassis; degradation of electronics (microchips, GPS) due to radiation; changes in the properties of lubricants and rubber seals; and the loss of protective properties of armor due to radiation-induced chromium segregation. It justifies the necessity of predicting the residual resource of equipment in combat zones.
Theoretical implications. The research deepens scientific knowledge regarding the synergistic effect of chemical degradation and radiation hardening on the survivability of WME systems. It develops a comprehensive approach to evaluating RSD in structural materials, such as MIL-A-12560 armor steels, under modern combat conditions.
Paper type. Research.
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References
Kenik, E. A., & Himes, M. J. (1981). Radiation-induced segregation in alloys investigated by electron microprobe. Journal of Nuclear Materials, 100(1–3), 121–133. https://www.sciencedirect.com/journal/journal-of-nuclear-materials
Bruemmer, S. M., Soran, T. F., & Henager, C. H. (1990). Radiation-induced segregation and intergranular corrosion in irradiated nickel-base alloys. Corrosion Science, 30(2–3), 291–299. https://www.sciencedirect.com/journal/corrosion-science
Nastar, M., & Soisson, F. (2012). Modeling of radiation-induced segregation. In R. J. M. Konings (Ed.), Comprehensive Nuclear Materials (Vol. 1, pp. 447–485). Elsevier. https://doi.org/10.1016/B978-0-08-056033-5.00035-5
Kassner, T. F., et al. (2007). Irradiation-assisted stress corrosion cracking of austenitic stainless steels in LWR core components. OECD Nuclear Energy Agency. https://www.oecd-nea.org
Skorokhod, V. V., & Ragulya, A. V. (1994). Sintering at controlled rate as a method of microstructure control in ceramics and similar powder-metallurgical materials. Powder Metallurgy, (3–4), 1–10. https://www.tandfonline.com/toc/ypom20/current
U.S. Department of Defense. (n.d.). MIL-STD-1501: Chromium plating and electrodeposition. https://quicksearch.dla.mil
Gündüz, S. (2019). Mechanical behavior of welded joints of armor steel fabricated by semi-automatic arc welding using nickel–chromium and low-alloy filler metals. Journal of Materials Research and Technology. https://www.sciencedirect.com/journal/journal-of-materials-research-and-technology
Karabacak, A. (2020). Classification of modern armor steels: History, material properties and heat treatment procedures. Materials Today: Proceedings. https://www.sciencedirect.com/journal/materials-today-proceedings
Davis, J. R. (Ed.). (2001). ASM specialty handbook: Stainless steels. ASM International. https://www.asminternational.org
Sims, C. T., Stoloff, N. S., & Hagel, W. C. (Eds.). (1987). Superalloys II: High-temperature materials for aerospace and industrial power. John Wiley & Sons. https://onlinelibrary.wiley.com
Nickel Institute. (n.d.). Role of nickel in stainless steel. https://nickelinstitute.org
Porter, D. A., Easterling, K. E., & Sherif, M. (2009). Phase transformations in metals and alloys (3rd ed.). CRC Press. https://doi.org/10.1201/9781439883570
Callister, W. D., Jr., & Rethwisch, D. G. (2018). Materials science and engineering: An introduction (10th ed.). John Wiley & Sons. https://onlinelibrary.wiley.com
Shewmon, P. G. (1989). Diffusion in solids (2nd ed.). TMS. https://www.tms.org
Gangloff, R. P., & Somerday, B. P. (Eds.). (2012). Gaseous hydrogen embrittlement of materials in energy technologies. Woodhead Publishing. https://doi.org/10.1533/9780857093899.
Nagumo, M. (2016). Hydrogen embrittlement: Fundamentals and modeling. Elsevier. https://doi.org/10.1016/C2014-0-00215-9.
Lynch, S. P. (2012). Hydrogen embrittlement phenomena and mechanisms. Acta Materialia, 60(9), 3513–3530. https://doi.org/10.1016/j.actamat.2012.03.022.
Smigelskas, A. D., & Kirkendall, E. O. (1947). Diffusion of zinc in alpha brass. Transactions of the Metallurgical Society of AIME, 171, 130–142. https://www.osti.gov
Darken, L. S. (1948). Diffusion, mobility and their relation to the free energy of vacancy formation. Transactions of the Metallurgical Society of AIME, 175, 184–201. https://www.osti.gov
Van Loo, F. J. J. (2004). The Kirkendall effect. Diffusion in Condensed Matter. https://doi.org/10.1007/978-3-662-05768-5_12.
Elzenbaumer, R., Fat, B., & Jäger, B. (n.d.). Intermetallic compounds in electronic packaging. https://ieeexplore.ieee.org
Rabkin, A., Taylor, W. R., & Van Loo, F. J. J. (2003). Reactive interdiffusion in solid-state bonding. Acta Materialia, 51(11), 3387–3397. https://doi.org/10.1016/S1359-6454(03)00145-9.
Pecht, M. G. (2011). Battery degradation in lithium-ion batteries: Fundamentals and applications. Artech House. https://us.artechhouse.com
Lux, S. F., Lucas, I. T., Pollak, E., et al. (2012). Mechanisms of lithium-ion battery degradation. Journal of Power Sources, 215, 54–60. https://doi.org/10.1016/j.jpowsour.2012.05.020.
U.S. Department of Defense. (n.d.). MIL-STD-1501: Low embrittlement chromium plating. https://quicksearch.dla.mil.
ASTM International. (2017). ASTM F519-17: Standard test method for mechanical hydrogen embrittlement evaluation. https://www.astm.org/f0519-17.html
Aerospace Industries Association. (2018). NASM 1312-5: Fastener test methods—Hydrogen embrittlement. https://www.aia-aerospace.org
Defense Technical Information Center. (n.d.). Stress corrosion cracking in aircraft components. https://discover.dtic.mil
ASM International. (n.d.). ASM Handbook, Volume 11: Failure analysis and prevention. https://www.asminternational.org
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